Inferno #09
31 июля 2006 |
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Likbez - Batteries. History, such as the advantages and disadvantages.
From batteries of the past, recall the age of 20-th ... Probably the very first and very effective nye batteries (in weight) were based on acids, sometimes called lead (Pb - abbreviation of lead, usually indicated on the case of batteries). They received widely used in automobiles and some less formal devices. Are still used, for example, in disorder reboynikah. Such popularity is due to cheaper components (sulfides, lead) large capacity and power peregruzoch Noah "tolerance" and a very large number ispolzovaniya.A cycles of the shortcomings can be but remember the low efficiency, increase in dependence of power on the temperature (in the region STI low temperatures), explosion (Supply offered by the period of charge valves) nonlinearity, the strong dependence dependence of the internal resistance of the tank (Remaining charge). Some progress in development of these batteries are allowed vypu ramp and a fully sealed model (in UPS), and with high efficiency (little ap adjoint to 60%). The next step in our country became alkaline batteries, namely, Nickel-cadmium (abbreviated Ni-Cd). But was a very big trick. Firstly, they were produced in limited quantities, which gave rise to terrible shortages and repulsion gross manufacturers. And as has been limited Chen also issued face value, it is strongly reduced their popularity. But do not let them "Drown" a similar deficit in the dry batteries. Secondly, the whole nomenclature Tour of the battery was low power and respectively, belonged to the household Melo Chi. Batteries of this type have efficiency about 70%, a large number of cycles ISPO lzovaniya very low and stable internal rennim resistance, were more patient to low temperature. But their capacity was very small, and they had characterized the effect of memory which limited the power used and conceals some merit, but for effective use of required experience in his service. Generally, the illiteracy in the application of such things, which often We passed off as literacy, requires individual cuffs to the correspondingly tvuyuschih masses. But, if shorter ... Alkaline batteries have produced clearly weaker than (the same, disc: D 0, xx) and, on the basis of their typical characteristics, could serve as an excellent and long-According to "The nominal discharge current. And in this case with slight memory effect, and sometimes without him, because rated current in the best case (for "D 0.55 C) was 110 mA, but it is rarely where required. In larger load losses grew in the internal contacts and memory effect. And if you remember from rechargeable flashlights are known for D 0.26 D (with nominal discharge current 26 mA), in which this current 10-fold greater, problems with using D-type batteries after absence of unreasonable technical progress quite understandable. And the most shameful, still going on ... Well, today penlight batteries have a very powerful output characteristics and high Coy capacity, but retain the disadvantages of accumulative mulyatorov the past, in the long- given up power. It should be noted that this is an accumulative mulyatorah in masse.I those who want to say that we have produced, and other types pain Shay Power, should withhold its ardor. I do not refute the existence of others, but accessible and familiar to many consumers they were not! Only in recent years, alkali nye batteries were successfully compete vat on the automotive market with acid, and in fact in Developed countries are already using lithium curves ... Cellular market is seriously promoted Battery progress due to increased capacity requirements while maintaining the company ktnosti. Next step: a nickel-metal-guide hydride batteries (NiMH). They use compounds of hydrogen with alkali metals - Hydrides, the same ones who used to satellites for a long time, and maybe even now use ... Thanks to high energy STI of chemical bonds, the capacity of the camp dard elements ("AA", "AAA"-type and about sneeze) has increased markedly, and output increases las, decreased internal resistance, and almost disappeared memory effect. In general, all characteristics characteristics has increased, and efficiency exceeded 70%. Perhaps the producers and overestimate some rye characteristics, for example, the value of it bone with full discharge when the NAM mummers falls much below the nominal. Personally, I have a razor worth NiCd accumulators torus of some Chinese firms such as "Fayi ryan - do not remember exactly - at 1.2V 500mAh, and works like a beast at a current of more than 2 amps Paying though not all, but almost all of its energy, and I can not believe that modern "AA" greater capacity will also be the same serve and will die soon ... Finally, lithium batteries, litiyionnye (Li-ion). The next jump capacity and power, as well as improvement of other parameters parameters. Likely, there also are used hydrides and, possibly, on the contrary, complex compounds equations that can respond quickly, vysvo bozhdaya tremendous energy. Ease of distribution decay can explain the high sensitivity The intensity of these batteries to peregrevu.Obla Dai's something like a powerful ionistora (con capacitor is very large capacity - Faraday but low-current) and generating high currents, Such batteries are very dangerous GOVERNMENTAL. I think many people know how to "shoot" for the closure of large capacitors, charged to high voltage (stock emaya in its energy is proportional to the square that stress), and in fact the energy in them nothing zhna before lithium battery. It is easy guess what the effect will be under such discharge akkumulyatora.Po fact, any explosion - a rapid release of a large number properties energii.No as decay products electrochemical reactions are not gaseous, energy is mostly thermal and melt the battery inside. Generally on Each battery has a warning - Do not short ends, and most about Explosion (mostly heating). If we trace the progress of battery it is clear that with the reduction of their domestic resistance fall of inertia on impact energy increases explosive nost.V particular, the old acid accumulates oscillator and could boil, and then another and worked, and today may die in few sekundy.Zamykat just as harmful and Conder - in all cases the energy is partially destroys your vehicle, reducing its characteristic characteristics and life sluzhby.Kogda something I locked one of the GP Battery 1500 mAh "AA" from of the player (not switched probe tester with limit of 10A on the base), and, apparently, since then the total operating time was reduced. Not price of capacity and cost of internal resistances resistivity, which increased markedly. Although I do not remember which of the two locked, one load noticeably stronger squander, and in fact has closed for a couple of seconds - no more more ... For a typical lithium battery large EMF, ie, they immediately generate a voltage of its face value and do not consist of multiple connected components, both pro The presence of the batteries. In the old cell phones tries (BOSCH) used lithium accumulator oscillator without the protection scheme, although the identification diffraction resistor and a temperature sensor. Poe Moreover they are easy to damage the circuit. Actually, the bombing is one such dead, I learned about his vnutrennostyah.V metal Scoy bank (sealed) is placed a set of plane of alternating electrodes and that is all in the medium of a spirit or something Poho zhego, dolgosohnuvshego. Easier to think that this capacitor ... Maybe everything is so unclear looked because he was dead and vzdu tyy.No interestingly, the leak was not broken, and at autopsy there was a sound gaza.Da passing, he's really reminiscent Minal capacitor. Fully razlomav concentration containers, I found two coiled metal cal tape (from the end they look like set of plates). It looks like aluminum and copper. They dried up black burst duration and substrate (something like), polyethylene, which Thoraya not what separates the metals, not what their na algebra, coiled into two layers. Of course, electricity chemical emf given pair of metals is very small, but added to them EMF salt (either Reagent), lithium-based, allowing achieved a lot of stress. Lack of serial connection of elements (and a corresponding imbalance of their characteristics tick) excludes the corresponding losses operation and makes the battery much reliable. A huge area of metals and therefore, dramatically reduces the reagent inside friction resistance with losses. As it happens in general, and everywhere Loss, as we know, there's always ... If consider the process of energy generation in batteries, we can note the presence The presence of balance, however, as in most other methods of obtaining energy. In our case, there is always the so-called emaya surface (or subsurface) capacity, and it postponed the generated my chemical reaction charge. Charges from imposed on the tokosbornikah (usually metal tals, alloys and coal), with which later on stepping into the load. They represent classical electron and hole (correct say - lack of electrons). Directly respectively adjacent to the layer tokosbornikam (Reactant / electrolyte) of polarized opposite signs and have ions of substances. But the most important thing is that the chemical reaction no load is essentially not happening, she was suppresses the very capacity to EMF tokosbor tors. Balance comes when the energy cally advantageous to maintain the original chemical components than to get their reaction ene rgiyu, almost equal to the energy coping EDS capacity. How so? After all, the source energy bounded Romney? Yes, it is huge, and contained in the mass, volume of the battery, but the reaction occurs at the interface of reagents - substances. On of the border, which has collected charged nye iony.Elektricheskoe ion field compensated EMF of a fixed capacity by means of current collectors property adjacent chains of ions, transmitter sign of the charge and the vector field through the entire mass agents - from the current collectors on the boundary Section substances. When under load current of the stack exists, and the voltage across the capacitor current collectors falls, the balance is disturbed, and energy more advantageous to react as Origin of runs to establish a regular balance. But the number of charged ions in the medium parameters yields and, consequently, increases the resistance lenie.Padaet and conductivity of the medium from Toko puller to the boundary problem reaktsii.Umenshenie weakly charged ions and the partial dilution of medium-neutral reaction products reduces the tension at the interface and makes it more sensitive to EMF eat bone. Accordingly, the balance occurs at lower voltage batteries. This is due to voltage drop in the operation. In addition to this there is ion exchange, and charged, Unspent reagents from the general masses moving towards the border of the reaction. But the rate of ion exchange is limited and, accordingly, Correspondingly, the peak power, too. When O & M atatsii it falls due to lower overall charge density, According to "The aforementioned prichinam.A large currents of energy literally consumed by ion exchange, but forced - under the influence of the discharged field strength at the border, as opposed to the fall EDS capacity. Closer to full charge element ktrolity diluted neutral products Tami reaction, further reducing the ion exchange Men and power. Throwing power "rested" source mainly due to the capacity to Toko strippers, and rising tension - concentration centration of the ionic charge, "crawl" on bound reactants. Also holds repolarization. This occurs near the end of the discharge. When Snee approximation of concentration of carriers (ions) of already reacting substances (representing ing the bulk) can be degraded again potential difference on the boundary and potential scrap discharge current collectors, creating a gap an interim sloy.Sloy not just high-resistance, and reduces the output capacitance of EMF, as frozen razhivaet chemical reaction like a mouth novivshemusya balance. With time (leisure element), this layer is destroyed - and the balance shifts, and the voltage is restored, but the loss is, of course, not to return. Repolarization is possible at a low concentration concentration of charged ions and large (from with respect to the remaining capacity) currents. Tor Yes ions are not able to effectively bridge resistance of the neutral decay products Yes, that leads under the current time rise to a number of internal protivoEDS. Of course, not peculiar to any repolarization Bohm composition and depends on the batteries of. It is worth mentioning that it is stipulated bone - it's instantaneous capacity of current collection Cove. She is also determined by the surrounding layer of reagents, as well as the overall electric Coy circuit elements across the border reaction Since the electric field at the difference potentials present in the whole chain pi. But the charges of the load drains directly directly with the current collector, and only those who really are present. In the process operation changes the chemical composition near the current collectors and, accordingly, their capacity, because polarization is determined more adjacent layer of substances. Of course, the capacity current collectors is falling. But not like other characteristics, since the polarization involved have a neutral substance - not participating in the reaction, and also provide capacity (Albeit weaker). One should not confuse a "capacitive" on polarization of repolarization. Last is a more powerful and orderly a level that discourages charged ions. A capacitive polarization is more diverse and high resistance, it is interspersed with charged ions and does not have its own strong field. In some cases, before the ion exchange represented a return of the charges, which is much faster and more reliable than the exchange of particles ve stances. Applied to the battery and ac kumulyatoram the above process is slightly On different for different types. Climb polarization characteristic of NiCd batteries, which leads to the effect of memory (for large operating currents) as well as for some powerful (mostly alkaline) elements Comrade at the end of their service. Example: battery PHILIPS (size "AAA") POWERLIFE XXL. By the way, an excellent example of quality, sohrannos Tea and impact that is typical for PHI LIPS. It works great, reducing the EMF in approximately to 1, then it may be full drop down to 0 and even less (if series connection of several elements), followed by recovery EMF after reducing / off current. Time recovery and the variation of EMF depend on the current status and operation. Repolarization polarization leads to some bounce Emf in the transitional managering, but it all about stitelno almost shrunken element. Typically, the batteries can be divided into alkali chnye and salt. The latter were popular in our country in the last century, since the other elastic was not. Saline batteries very high koomnye and are designed for weak load - receivers, sensors, key chains and other drebe den.I although these batteries also differ Xia composition, capacity, and power (internal resistance), their impact towards the end of EC spluatatsii put it mildly, is bad, which is considerably in low-voltage devices. Electromechanical nical clock starts stumble at EDS greater than 1 (often as much 1.3), although there may work with the EMF is less volta.Pri that Hours - the weakest load, average current - share mA, enough to tuck salt Battery capacity in the hundreds or thousands of uF and cha raw safely go. A similar situation with inf rakrasnymi panels (LG TV) and battery size "AA" POWER ACE (almost a shame!). When EDS has run down (about 1.4) remote blocking is open to the LED switch and about sazhivaet batteries before their trip. When rank in a large ripple because of the high internal resistance, although the consoles yn poisoning - a whole load average, and the currents outbreaks are very large. Capacity cheap salt batteries (2-3 rubles) goes from 450 mA hours, but give they are noticeably smaller, and in some cases a third - Despite what a load. The balance of power can be used on weak instruments, and then not at all ... Saline batteries property Nene slow ion exchange, as well as neposreds idents participate brushes Zn - zinc (Usually) in energy production and its consumption, What happens as a result of swelling and corrosion housing, pollution, food compartments. So elements characteristic of a marked swing Emf in the operation (in addition to the fall in internal resistance), which again due to slow ion-exchange. Well-known labels on the elements - the absence of cadmium and mercury (0% mercury, 0% cadmium) - explains the concern for the environment distorting medium. Company shall notify the buyer of products as environmentally product purity, despite the fact that the characteristics of the element may be vysote.Delo that mercury noticeable but improves the impact, reducing the internal SOPs rotivlenie, even with negligible small doses, and cadmium, among other things, increases total capacity. This is the easiest way which is used by some manufacturers batteries. But while the availability of data ve substances must be indicated (for mercury More and percentage). For example, elements ment HV - HI WATT ("AA") has a symbolic Cd and a ban on the free disposal - ne recherknutuyu urn (like all batteries; wondering where did they take?). And on the other Batteries do not remember the company, perhaps once novidnost MINAMOTO (red building), was indicated mercury content less than 0.015%. However, the presence of inscriptions HEAVY DUTY for at presence of the inscription and 0% Mercury 'Cadmium may conceal different. As well fabricated branched powerful element with no data Easley march (using safe additives) and counterfeiting, ie, simple saline element ment. Cadmium elements can be much easier and less common at the same capacity. Well, linden strip test (Nari Owl to the body, instead of the original y DURACELL), no doubt, many people have seen - a good way to fool the illiterate buyers who have heard something about the original. Of course, the alkaline elements (they are not always so have the inscription ALKALINE, although this prize nak firm pointed to as a fact of a new type) surpass any salt. For these properties tively stable, non-return, lower EMF and excellent energy efficiency, which allows exists to judge the extent of their razryada.Nesmotrya on capacity and orientation to a powerful load they effectively serve for any discharge. Y these elements brushes are not spent during the operation (in fact it is Origin of walks, but anyway). Elements themselves are more ger metichny and environmentally friendly (of course, the quality governmental samples). Persistence (also in quality) is very high. Grounded power 'loading element is very long and effective effectively can nourish the weak (the same PHILIPS) - And therefore on such batteries do not happen inscriptions, describing their impact - it itself a fact. Producers seek to make them more energy efficient and comfortable - same DURACELL. But indicates the time the case zhby - ten times longer (with a note - on Compared to conventional batteries, salt) - Achieved by including power, low Kim resistance to alkaline electrolyte, rapid ion-exchange, which stably der contains the EMF, feeding device, even at the end of the ex exploitation, while the salt does not potya no closer to the end ... Currently, the most expensive and (Bu Dimo) energy is DURACELL ULTRA M3 (if not mistaken the name), which ("AA") is in Ryazan, about 25 rubles, but I I doubt that it is more than 3 ampere-hours. But It should be noted that at equal (with NiMH battery) battery capacity will be pa bot longer t.k.vse as powerful and possessing em high EMF, and hence the energy that appreciably affect the time of joint ables player with internal impu lsnym converter, which, of course camping, pumping out the battery is not current, and power. Expensive items in most cases advantageous to use (compared to de shevymi), especially in the "not weak" devices: flashlights players. Although in the past, with frequent use, the batteries still more profitable and quickly pay off. Dear, alkali elements are more practical - bought widely regarded as one time for a long time, more environmentally friendly - ME nshe debris from one powerful, than from carrying How many of the weak. Salt, cheap, little between are different, and often cheap counterfeit vayut and overpay for them anyway, that take the cheapest. Expensive fake rare, and in reputable shops are well worth it (Unless, of course, without excessive mark-ups) - and DURACELL with this test strip is not raises doubts as I have long kachestve.Lichno advanced batteries in the priority (not least because of the environmental - no unnecessary waste - batteries). But he sometimes buy cheap, if not permanently need (batteries sat down, and no place to recharge). But back to the lithium battery. Apparently, they use charge ion exchange and a few energy levels it (although in the latter, I could be wrong). A as the internal charge density falls during the discharge, the resistance increases, there is little carriers - and this leads to losses (as always). But because of the vast area of current collector plates, it becomes noticeable only at the end of the discharge. Basically, there is resistance due to the finite speed of transition processes of. Current EDS also determined by the strength of the charges at the boundary of the interaction of reactants and depends on density and cumulative energii.Eto as and alkaline (which can be attributed NiMH batteries), leads to dependence current EMF of stored energy, ie to gradual decrease in stress at times series. This dependence is, as always, is violated is in the end, when, because of low density ostavschihsya charges (ions) bound reagents Comrade can not be quickly filled, tense dent - and EDS, too, recovering no-load, approaching the nominal value cheniyu (3.6), but in the end again depending on the balance tank (balance neutralization lnyh and charged reagents). Apparently, in lithium batteries moving charges, but not the ions, and concentration concentration of charges in the amount of reagents in leads to an accumulation tank. Based on the crystal curve of the discharge (of some of its non-linearity) You can suggest a few ene rgeticheskih levels for the concentration of charge Yes, in ions. This allows partially considered regarded this as a giant battery capacitor, but with nonlinear capacitance and additional features. Most non-linearity in the small charge de (top performance) - EDS quickly increases to the rated voltage of the former connected component, reminiscent of charge on a capacitor, and then rapidly "saturated", and the increase falls almost to zero, as capacity "capacitor torus "has increased dramatically in a very large number raz.Tehnologicheskoe performance as a capacitor - a lot of parallels lnyh facings or lenta.No charges of shooting are only from the edge of the brushes (technologists cally - a compact solution, which is impossible possible way around) - as in the electrolyte, which limits the drive capability peak current. This means that with increasing capacity of the battery internal resistance tion falls slightly, because for sufficiently parameters to the new charge passes through the layers of energy transfer leads a long way to the brushes. Of course, there is a definite relationship - the more parallel plates, the lower the resistance tion, and the broader plane of the lifting charge - so also the resistance less - all of are known the calculation of resistance provodnika.No as actual sizes are limited, it is impossible reduce the resistance as effectively as well as build capacity. The above refers to a single form factor - batteries for cellular - and th vorit that occurs with increasing capacity leads a smaller increase in the power battery (Due to a smaller decrease in losses). But Fortunately, most power sotikah not required. Someone can refute - that discharged batteries, and a very large then com, and I do not deny it, but losing some value sive, and the normal operation of such can not be named! I've seen batteries with a nominal voltage value 3.6, 3.7 and 3.8, and This means, the electrolyte can differ chatsya, providing a different value EDS.No, actually, that means the nominal? In contrast Unlike other batteries, it is minimal significance, in which the battery is still effectively gives up energy (it can be seen from weak current discharge curve). With powerful load due to internal losses, the voltage of gradually decreases, reaching even the smaller (The difference to a few tenths B) values motion, after which the EMF decreases rapidly and ak kumulyator off. Thus, it is more "honest" batteries, which feed on load is very high EMF. In fact, in battery is a very significant charge, but under the influence of a powerful load and Drawdown of EMF protection circuitry shuts it down before he would give his full zaryad.Kone chno, the balance is not great, but if kratkovremen but to submit to external, then the charging ka (to include the battery), it is still up LHA will be working on a weak load times ryadivshis almost entirely in the moment of switch off radiation. You can continue to "run" his impu lsami external current, watching as EMF tends to the nominal value of no load (going pererasp definition of the charges and how to transform balance of energy in the higher EMF). resistivity resistivity battery is not so much on exceeds. Of course, if you try to charge based on Consequently stranded battery, losses will be more than if you do it with just a shrunken (Noticeable at high current charge). This is a ve RNO for all batteries. It is also true that the deep discharge can be deduced from damage the battery (including subsequent powerful charge), since the weak polarization tion of reagents leads to a violation of the border reaction, the mixing of the electrolyte and the appearance leniyu additional internal losses and leaks. Fortunately, for Li it is shown in lesser extent - because of ion technology and high quality production (actually cally they have no protection, where possible defects electrolyte - only the plane of polarization tion). But a delusion is not necessary, current pain large losses wear out the battery, they do not should get involved! Excess electric field for a given GOVERNMENTAL chemical compounds cause the current Ute points (energy is not accumulated) and can destroy the current collectors. A loss of leaks may overheat the battery, causing it destruction. Perhaps because he died accumulators torus my sotika (old BOSCH), it does not was the protection circuit. Probably because of the high the cost of Li batteries have to supply "Personal" protection scheme. I think it is not one battery is already saved (in fact BOSCH exploded electrolytic chip con- condenser and closed circuit and the battery is first could not stand it no one was turned off). Different types of batteries contain time nuyu stuffing, in some cases, additional rated - the third contact can be found identification tification resistor (strictly defined par), sometimes it thermistor, on to toromu intelligence Phone judges corrected particular battery. There are also 4 - and 5-pin ktnye batteries (and identification, and ter modatchik, and maybe something else ...), and schemes inclusion appendage and are positive, and minus, and both polyusam.A capacity decree to not always (link to standard), and it remains tsya measure it experimentally. In the first experiments, I thought control circuit disconnects the battery, for meryaya voltage across the external terminals, rather than the battery itself (it's easier to implement trigger effect). But a little later, when I opened the battery is defective and able to measure it directly, came to different conclusions. Of course, different companies, different types of its own security implementation, and lzya exclude that in some tension measured before and after the key and algorithm protection may vary. But in most cases, you can draw the following conclusions. Overview (a comparison in general) Pb pluses More power capacity at an affordable (Per unit of capacity) price. To withstand serum overload, not badly damaged, "Repeatedly" and termovynoslivy in general ... Pb cons Large energy losses (at a charge) rather big size, high heat-capacity dependence of the power. Ni-Cd pluses Good termonadezhnost power and not bad weight and size characteristics. You supported the unlimited recharging weak current (percentage of capacity, in any case tea - our old, disc batteries - almost a proven fact). Good efficiency operation at low currents. Ni-Cd cons Easily destroyed under short-circuit SRI markedly reducing their performance. Manifestation of memory when dealing with more lshimi currents (at the time of discharges / charges). Yield (relative) for pico howling power Pb. While, the qualitative research complement, modern batteries are comparable ble to Pb. Ni-MH pluses Good power and capacity, with a small large scale fast zaryazhaemost. High cue efficiency (up to 80% at low currents). Hundred stability of the impact, low resistance when proper operation. Ni-MH cons The high price (mostly because of emkos TI), a manifestation of memory at bolshoh currents in a number of operational GOVERNMENTAL sluchaev.Ne withstand short-circuit Kania, impairing their properties. Li-ion pluses Compactness, high efficiency, large power In particular, a large EMF with stable returns, large capacity for its size, the perturbation zhnost very fast charge (at the expense of efficiency) and avtokommutatsiya (with built-in scheme). Efficiency for 10-hour currents over 98%! For clockwise Output currents of more than 85%. Li-ion cons High price (because of technology and natsen s). Can not withstand superheat (60 ° C) and overload (although admit a very large currents - and avtokommutatsiya protects ...), replaced TNO reducing their options, sometimes leaving failure. Afraid of physical attacks and strong FIR impacts, because technologically Accu Conversely made and will not tolerate domestic defects due to external effects - to shorter than: they must be handled carefully. Li-pol (not exactly sure how to denote, seen live ...), presumably on possess the same plusses and minuses, and that Li-ion, but more succinct (technologically), and therefore, more expensive, and sensitive to the physical - impact, pressure. KSA-7G
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